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http://dspace.cus.ac.in/jspui/handle/1/6363| Title: | Inter-ligand azo (NvN) unit formation and stabilization of a Co(II)-diradical complex via metal-to-ligand dπ–pπ* back donation: synthesis, characterization, and theoretical study |
| Authors: | Rakshit, Richa Ghorai, Samir Sarmah, Amrit Tiwari, Archana Royb, Ram Kinkar Mukherjee, Chandan |
| Issue Date: | 2015 |
| Publisher: | The Royal Society of Chemistry |
| Citation: | Dalton Transactions V.44 (8), 2015, 3724–3727 pp. |
| Abstract: | An azide (–N3) group attached at the -ortho carbon atom to the aniline moiety of 2-anilino-4,6-di-tert-butylphenol formed a diradical-containing Co(II) complex via inter-ligand azo (N[double bond, length as m-dash]N) bond formation. Metal-to-ligand (azo), dπ-to-pπ* back donation stabilized the metal in its lower oxidation state. |
| URI: | https://doi.org/10.1039/c4dt03214d http://dspace.cus.ac.in/jspui/handle/1/6363 |
| ISSN: | 1477-9226 |
| Appears in Collections: | Archana Tiwari |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| c4dt03214d.pdf | 637.52 kB | Adobe PDF | View/Open |
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